In light of the worldwide movement toward renewable energy sources, there has been a substantial emphasis placed on the effectiveness and durability of solar photovoltaic (PV) systems. In addition to the many different modes of deterioration that might have an impact on the performance of PV modules, acidification is becoming an increasingly important worry. The process of acidification is characterized by the formation and accumulation of acidic compounds within photovoltaic (PV) modules, which ultimately leads to a variety of forms of degradation that ultimately results in a loss of performance. In this article, the causes, methods, and repercussions of acidification on photovoltaic cell modules are investigated. The study also provides a complete explanation of how this phenomena can compromise the generation of solar energy.

A Definition of Acidification in Photovoltaic Modules and an Understanding of Its Causes

In the context of photovoltaic modules, acidification refers to the process by which acidic compounds are formed within the encapsulant, backsheet, or other components of the module. Several other sources can be the origin of these acidic chemicals, including the following:

Hydrolysis of encapsulant materials: Under certain circumstances, certain encapsulants, such as ethylene vinyl acetate (EVA), are capable of undergoing hydrolysis, which results in the production of acetic acid.

Pollutants from the environment: Pollutants from the environment, such as sulfur dioxide (SO2) and nitrogen oxides (NOx), which are produced by industrial emissions, have the potential to enter the module and react to generate acids.

In addition to chemical processes, corrosion: Acidic by-products may be produced as a result of the corrosion of metallic components contained within the module.

Acid Formation Mechanisms and Mechanisms

Hydrolysis of EVA: EVA, which is a typical substance used for encapsulation, has the ability to hydrolyze when exposed to high temperatures and moisture, which results in the production of acetic acid. In this way, the chemical reaction can be described:

By combining EVA with H2O, an acetic acid (CH3COOH) is produced.
EVA+H 2 O is a compound that can be converted into an acetic acid (CH 3 COOH).
Temperatures and humidity levels that are greater both contribute to the acceleration of this process.

Penetration of Pollutants: Pollutants such as sulfur dioxide and nitrogen oxides have the ability to pass through the encapsulant and react with moisture to produce sulfuric and nitric acids.

Hydrogen sulfide (SO2) and hydrogen peroxide (H2O) are the products of the reaction.
SO 2 + H 2 O → H 2 SO 3 (sulfurous acid) are the products of the reaction.

The reaction between 2NO2 and H2O results in the formation of HNO3 and HNO2, which are both nitric and nitrous acids.
Nitric and nitrous acids are produced by the reaction of 2NO 2 and H2O, which results in the formation of HNO 3 and HNO 2.
The Products of Corrosion: Components made of metal, such as solder joints and connectors, are susceptible to corrosion, which results in the production of acidic compounds that further accelerate the deterioration processes that occur within the module.

Effects of Acidification on the Performance of Photovoltaic Modules

1. The deterioration of contacts made of metal

The corrosion of metallic contacts and interconnections within photovoltaic modules is accelerated due to the presence of acidic conditions. The corrosion causes a rise in the electrical resistance, which in turn leads to an increase in the series resistance and a decrease in the electrical efficiency (efficiency). Additionally, the deteriorating connections generate possible failure locations, which can result in open circuits and the failure of the module as a whole.

2. The deterioration of materials used for encapsulation

Chemical degradation and discolouration of the encapsulant are both caused by the production of acids within the material that makes up the encapsulant packaging. As a result of this degradation, the optical transparency of the encapsulant is reduced, which in turn reduces the amount of light that is able to reach the solar cells and consequently decreases the power output of the module. Discoloration, also referred to as “browning,” is a distinct manifestation of this process that can be observed.

3. The process of delamination

Because of the presence of acidic conditions, the adhesion between the various layers of the photovoltaic module, including the encapsulant, solar cells, and backsheet, can be compromised. It is possible for this weakening to develop in delamination, which is the separation of layers, which results in the creation of air gaps that further decrease the structural integrity and electrical performance of the module. Delamination can also make it possible for more moisture and pollutants to penetrate the material, which can exacerbate the effects of other degradation mechanisms.

4. PID, which stands for potential-induced degradation

Potential-Induced Degradation (PID) is a process that occurs when voltage differentials lead to the creation of leakage currents. Acidic conditions can make PID worse. It is possible for the presence of acids to increase the mobility of ions within the encapsulant, which in turn increases the probability of PID occurring. The result is an additional decrease in performance as a consequence of shunting channels and a reduction in electrical insulation.

5. Deterioration of the Backsheet

Electrical insulation and protection against external conditions are two of the most important functions that the backsheet of a photovoltaic module serves. In the presence of acidic substances, the backsheet material might undergo degradation, resulting in a decrease in its mechanical strength and insulating characteristics. The failure of the backsheet can expose the internal components to the environment, which can result in the exposure of electrical dangers and subsequent loss of performance.

Preventative measures and strategies for mitigating the effects

1. The Selection of Materials

When selecting materials, it is essential to select those that have a higher resistance to hydrolysis and acid production. The resilience of alternatives to EVA, such as polyolefin (POE) encapsulants, to the deterioration caused by moisture and heat is significantly higher. Additionally, backsheets that are constructed from materials such as fluoropolymers offer excellent protection against the degradation caused by acid compounds.

2. Methods of Encapsulation That Have Been Improved

It is necessary to have advanced encapsulation techniques that can limit the amount of moisture that enters the system and guard against environmental pollutants. Among these methods are the utilization of edge seals and multi-layer encapsulants that provide enhanced barrier qualities. These approaches are employed in order to prevent moisture and pollutants from entering the module.

3. Controlling the Environment

There is a significant reduction in the risk of acidification that can be achieved by installing photovoltaic modules in locations that have maintained humidity levels and limited exposure to industrial contaminants. When it comes to large-scale installations, the implementation of air filtration and pollution control systems around the installation site can help reduce the impact of pollutants that come from the outside.

4. Scheduling of Routine Inspections and Maintenance

Inspection and maintenance of photovoltaic modules on a regular basis can assist in the detection of early indicators of acidity and other mechanisms of degradation. Monitoring systems that keep track of performance metrics and environmental variables are able to provide early warnings, which enables prompt intervention and repair to take place.

5. Coatings that provide Defence

For the purpose of preventing corrosion and the production of acidic by-products, protective coatings can be applied on metallic contacts and connectors that are contained within the PV module. As a result of their barrier properties, these coatings reduce the amount of interaction that occurs between metal surfaces and environmental conditions that result in the creation of acid.

Various Case Studies and the Results of Research

The first case study focuses on the effects of acidification in coastal areas.
According to the findings of a study that was carried out on photovoltaic (PV) installations in coastal regions, modules that were subjected to high levels of humidity and salt spray demonstrated considerable acidification. There was a significant decrease in performance as a consequence of the corrosion that occurred in the metallic components. In order to lessen the impact of these impacts, the research suggested employing procedures that are more effective in encapsulating and materials that are resistant to corrosion.

Comparative Analysis of Encapsulant Materials, the Second Case Study

The results of a study that compared POE encapsulants to EVA encapsulants under circumstances of accelerated aging revealed that POE encapsulants exhibited much lower levels of acid production and better resistance to hydrolysis. The fact that modules that contained POE encapsulants maintained greater performance levels throughout the duration of the test served to emphasize the significance of material selection in the fight against acidification.

Case Study Number Three: Environmental Control with the Aim of Mitigation

In order to lessen the amount of sulfur dioxide and nitrogen oxides that were present in the vicinity of the photovoltaic modules, an installation was carried out in an industrial part of the city. During a period of five years, the modules exhibited less indications of acidification and maintained a greater level of efficiency in comparison to a control group that did not utilize filtration, so demonstrating the efficacy of environmental management techniques.

Заключение

The efficiency and durability of solar cell modules are both significantly jeopardized by acidification, which poses a substantial concern. Copper corrosion, encapsulant deterioration, delamination, and accelerated potential-induced degradation are all potential outcomes that might be brought about by the production of acidic chemicals within the module. To effectively combat acidification, a multidimensional approach is required. This approach should include the selection of materials that are resistant to acidification, the implementation of advanced encapsulation techniques, environmental controls, and routine maintenance. It is possible for the solar industry to ensure that photovoltaic modules continue to supply electricity that is both reliable and efficient over the course of their intended lifespan if they understand the impacts of acidification and take measures to mitigate them. Optimising the performance of solar photovoltaic (PV) systems in a variety of climatic circumstances will require ongoing efforts to counteract acidification, which will become increasingly important as science and technology continue to progress.

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