はじめに

By increasing the impact resistance and toughness of engineering plastics, toughening agents play a crucial role in improving their mechanical properties. You can learn more about the various toughening agents that are frequently used in engineering plastics by visiting COACE. Selecting the best alternative to modify the properties of engineering plastics for diverse industrial purposes requires an understanding of these toughening agents.

Elastomers

Due to their outstanding energy absorption capacity and flexibility, elastomers are frequently utilized as toughening agents for engineering plastics. By diffusing inside the polymer matrix and absorbing impact energy, they function as microscale modifiers, enhancing the material’s toughness. Ethylene-propylene-diene monomer (EPDM), styrene-butadiene-styrene (SBS), and acrylonitrile-butadiene rubber (NBR) are examples of frequently used elastomers. Engineering plastics now have better flexibility and impact resistance, making them ideal for uses like automotive parts, sporting goods, and electrical enclosures.

Thermoplastic Elastomers (TPEs)

TPEs are a class of materials with characteristics shared by thermoplastics and elastomers. They retain elastomeric qualities while being melt-processable like thermoplastics. By creating scattered domains inside the polymer matrix, TPEs function as toughening agents, improving impact resistance and elongation at break. Styrenic block copolymers (SBCs), such as styrene-butadiene-styrene (SBS) and styrene-ethylene/butylene-styrene (SEBS), are frequently utilized TPEs. TPEs are used in medical equipment, consumer goods, and automobile parts.

Center-Shell Rubber Particles

A hard shell surrounds a soft rubbery center in core-shell rubber particles. Through the provision of an energy-dissipating mechanism during impact, these particles serve as toughening agents. While the hard shell improves compatibility with the polymer matrix and adherence, the soft core absorbs and dissipates impact energy. Engineering plastics are frequently used in automotive parts, electrical housings, and industrial applications. Core-shell rubber particles, such as acrylate-butadiene-styrene (ABS) and polymethyl methacrylate (PMMA) core-shell structures, are examples of these materials.

Engineering plastics can have their mechanical qualities improved through the use of nanostructured toughening agents, such as nanoparticles or nanofibers. By strengthening the polymer matrix with these nanoscale additions, stiffness, strength, and toughness are increased. Clay nanoparticles, carbon nanotubes (CNTs), and graphene are a few examples. High-performance composites, electronics, and aerospace all use nanostructured toughening agents.

インパクト・モディファイア

Impact modifiers are frequently utilized as engineering plastics’ toughening agents. Through encouraging energy dissipation during deformation, they increase impact resistance. Acrylic-based impact modifiers, acrylonitrile-ethylene-propylene (AEP) rubber, and chlorinated polyethylene (CPE) are a few examples. Impact moderators are frequently employed in a variety of sectors, including consumer items, construction, and the automotive industry.

Fibrous Toughening Agents

To increase the strength and toughness of engineering plastics, fibrous toughening agents like aramid fibers and glass fibers are used. These fibers serve as reinforcement, enhancing the material’s resistance to impact and crack propagation. Fibrous toughening agents are mostly employed in structural applications, automotive components, and composite materials.

Reactive Toughening Agents

During processing or curing, reactive toughening agents chemically react with the polymer matrix, generating covalent bonds and enhancing interfacial adhesion. Examples include functionalized elastomers that increase toughness and impact resistance, such as epoxy-functionalized rubber. Applications for adhesives, coatings, and advanced composites frequently use reactive toughening compounds.

To improve the mechanical properties of engineering plastics, toughening agents are necessary. The several kinds of toughening agents were examined in this article, including elastomers, thermoplastic elastomers, core-shell rubber particles, nanostructured additives, impact modifiers, fibrous agents, and reactive modifiers. Enhancing impact resistance, hardness, and other desired attributes is possible with each type through various procedures and advantages. When choosing the best alternative to modify engineering plastics for certain industrial requirements, it is essential to understand the properties, restrictions, and common applications of these toughening agents. The variety of toughening agents and the engineering polymers for which they can be used will continue to grow as a result of additional research and development in this area.