はじめに

For better material performance in polymer blends, achieving strong adhesion between various polymer phases is essential. In polymer blends, adding fillers or additives is a typical tactic to improve the strength of adhesion between various polymer phases. By altering the interfacial characteristics and fostering interphase interactions, additives and fillers contribute significantly to improving adhesion strength.

活性化剤

It is common practice to use coupling agents to increase the adhesion strength of polymer mixtures. These substances have functional groups that can interact with both polymer phases, resulting in the formation of covalent bonds at the interface. Titanates, zirconates, and silanes are often used coupling agents. These substances boost interfacial strength and adhesion by acting as a link between the polymer phases and encouraging chemical bonding.

Compatibility Reactors

Reactive compatibilizers are additives made especially for immiscible polymer blends to increase adhesion strength. The reactive functional groups in these compatibilizers can react with the polymer chains in both phases to form covalent bonds across the interface. Reactive compatibilizers increase adhesion strength and stable blend shape by encouraging interfacial bonding.

Nanoparticles

The adhesion strength of polymer blends can be considerably improved by adding nanoparticles. Nanoparticles with a high surface area and distinctive interfacial characteristics include metal oxides, alumina, and silica. They can create chemical connections at the interface or physical interlocks with polymer chains to promote adhesion. Effectively enhancing the adhesion strength requires the dispersion and surface modification of nanoparticles.

Nanoclays

To improve the adhesion strength in polymer blends, nanoclays like montmorillonite, hectorite, or layered silicates are routinely utilized as fillers. These nanoclays can produce intercalation or exfoliation structures inside the polymer matrix and have a high aspect ratio. Strong interfacial interactions between polymer chains and nanoclays enhance mechanical characteristics and promote adhesion strength.

Nanocarbon tubes

Another type of filler that is used to improve the strength of adhesion in polymer blends is carbon nanotubes (CNTs). High aspect ratios and remarkable mechanical qualities of CNTs enable effective load transmission and interfacial reinforcement. The robust van der Waals interactions between the polymer phases and the CNTs increase adhesion strength and support improved mechanical performance.

Multifunctional Polymers

Maleic anhydride-grafted polymers, for example, are frequently employed as additives to improve the adhesion strength in polymer blends. These polymers have reactive functional groups that can interact with both phases’ polymer chains to form interfacial bonds. By increasing compatibility, lowering interfacial tension, and stabilizing blend morphology, functionalized polymers increase adhesion.

Interactions and Mechanisms

These additives and fillers improve adhesion through a variety of methods, including chemical bonding, physical entanglement, interlocking, interfacial tension reduction, and interfacial energy modification. Knowing these mechanisms makes it easier to choose the right fillers and additives for particular polymer blend systems.

Optimizing and Problems

To get the highest adhesion strength, it is essential to optimize the polymer blend’s additive or filler content, dispersion, and compatibility. To achieve efficient adhesion improvement, issues including filler aggregation, inadequate dispersion, and restricted compatibility must be resolved.

結論

A widely used method to improve adhesion strength across various polymer phases is to add additives and fillers to polymer blends. Common fillers and additions include functionalized polymers, reactive compatibilizers, nanoparticles, nanoclays, and carbon nanotubes. Researchers and engineers can choose appropriate ingredients and improve adhesion strength in polymer blends by understanding their properties, processes, and interactions.

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